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Priority permeable organic film is a kind of permeable vaporization film. The separated liquid components can be selectively dissolved and diffused. Relying on the pressure difference on both sides as the driving force, it passes through the film in a vapor state, and then condenses into a liquid to achieve the purpose of separation.The product is supported by an inorganic ceramic film and an organic polymer material as the selection layer. Through surface modification, the organic and inorganic interfaces have a very high binding strength.